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New osmium-based reagent for the dihydroxylation of alkenes.

Abstract:

The cis dihydroxylation of alkenes is most efficiently accomplished by reaction with osmium tetroxide. Recently, the expense and toxicity of osmium tetroxide have led to a number of attempts to harness alternative osmium-based reagents, including microencapsulation and solid support techniques. We describe here the development of a new nonvolatile, stable, and recoverable osmium-based reagent devised for the stoichiometric cis dihydroxylation of alkenes. Although attempts to make this new dih...

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Publication status:
Published

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Publisher copy:
10.1021/jo060301c

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Harris, RM More by this author
Butterworth, S More by this author
Burrows, JN More by this author
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Journal:
The Journal of organic chemistry
Volume:
71
Issue:
12
Pages:
4481-4489
Publication date:
2006-06-05
DOI:
EISSN:
1520-6904
ISSN:
0022-3263
URN:
uuid:5d2a611c-65d5-44a5-8ded-213f0ed59caf
Source identifiers:
33493
Local pid:
pubs:33493

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