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Reactions of Cyclopentadienyl-Amidinate Titanium Hydrazides with CO2, CS2, and Isocyanates: Ti=N-alpha Cycloaddition, Cycloaddition-Insertion, and Cycloaddition-NNR2 Group Transfer Reactions

Abstract:

We report a comprehensive combined experimental and DFT investigation of the synthesis, molecular and electronic structures, and reactivity of terminal hydrazido complexes with CO2, CS2, isocyanates, and isothiocyanates. Reaction of Cp*Ti{MeC(NiPr) 2}(NtBu) with hydrazines R1R 2NNH2 gave the structurally characterized series of hydrazides Cp*Ti{MeC(NiPr)2}(NNR1R 2) (R1 = Ph, R2 = Ph (13), Me (14); R 1 = R2 = Me (15)). The energetics of this imide/hydrazine exchange reaction, as well as the el...

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Publication status:
Published

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Publisher copy:
10.1021/om101167p

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Journal:
ORGANOMETALLICS
Volume:
30
Issue:
5
Pages:
1182-1201
Publication date:
2011-03-14
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
URN:
uuid:5c91ba1d-7a36-4bcd-8420-d6f0d802995c
Source identifiers:
127248
Local pid:
pubs:127248

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