Journal article

Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B center dot NH3 as probed by experiment and computation

Abstract:: Multiple metal-bound oligomers in the dehydropolymerisation of H 3B·NH3 have been observed by electrospray- ionisation mass spectrometry and NMR spectroscopy using the catalytic metal fragment {Ir(PCy3)2(H)2}+. A computational study suggests that sterics dictate whether multiple dehydrogenation/B-N coupling of amine-boranes H3B·NRR'H (R, R′ = Me or H) is observed, and also demonstrates the experimentally observed requirement for additional amine-borane to promote dehydrocoupling. This journal is © the Partner Organisations 2014.

Publication status:: Published

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APA Style

Kumar, A., Johnson, H., Hooper, T., Weller, A., Algarra, A., & Macgregor, S. A. (2014). Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B center dot NH3 as probed by experiment and computation. CHEMICAL SCIENCE, 5(6), 2546–2553.

MLA Style

Kumar, A., et al. “Multiple Metal-Bound Oligomers from Ir-Catalysed Dehydropolymerisation of H3B Center Dot NH3 as Probed by Experiment and Computation.” CHEMICAL SCIENCE, vol. 5, no. 6, Royal Society of Chemistry, 2014, pp. 2546–53.

Chicago Style

Kumar, A, H Johnson, T Hooper, A Weller, A Algarra, and SA Macgregor. 2014. “Multiple Metal-Bound Oligomers from Ir-Catalysed Dehydropolymerisation of H3B Center Dot NH3 as Probed by Experiment and Computation.” CHEMICAL SCIENCE 5 (6): 2546–53.
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Publisher copy:: 10.1039/c4sc00735b

Authors

+ Kumar, A More by this author

Role:: Author

+ Johnson, H More by this author

Role:: Author

+ Hooper, T More by this author

Role:: Author

+ Weller, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Algarra, A More by this author

Role:: Author

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Publisher:: Royal Society of Chemistry
Journal:: CHEMICAL SCIENCE More from this journal
Volume:: 5
Issue:: 6
Pages:: 2546-2553
Publication date:: 2014-01-01
DOI:: 10.1039/c4sc00735b
EISSN:: 2041-6539
ISSN:: 2041-6520

Language:: English
Pubs id:: pubs:466510
UUID:: uuid:5c619aeb-2708-4ddc-8d29-d641b6c68e30
Local pid:: pubs:466510
Source identifiers:: 466510
Deposit date:: 2014-06-17

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Copyright date:: 2014

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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