- Abstract:
-
Zinc dialkyldithiophosphates (ZDTPs) are widely incorporated in lubricant formulations as antioxidant and antiwear additives. Using the model compound zinc n-dibutyldithiophosphate (Bu-ZDTP) in dimethylformamide (DMF) solution, cyclic voltammetry is applied to a detailed study of Bu-ZDTP electro-oxidation. Bu-ZDTP is shown to be oxidized in a chemically irreversible electron transfer process under diffusion-limited conditions. A similar study of Bu-ZDTP reduction revealed nucleation of zinc a...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1149/1.1391978
-
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- Publisher:
- Electrochemical Soc Inc
- Journal:
- JOURNAL OF THE ELECTROCHEMICAL SOCIETY
- Volume:
- 146
- Issue:
- 7
- Pages:
- 2598-2605
- Publication date:
- 1999-07-05
- DOI:
- ISSN:
-
0013-4651
- URN:
-
uuid:5c1e2283-1915-4cf6-938d-79dad6b8200d
- Source identifiers:
-
37036
- Local pid:
- pubs:37036
- Language:
- English
- Copyright date:
- 1999
Journal article
Electrochemical studies of the automotive lubricant additive zinc n-dibutyldithiophosphate
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