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Experimental and theoretical Mossbauer study of an extended family of [Fe8(μ4-O)4(μ-4-R-px)12X4] clusters.

Abstract:

Six [Fe(8)(μ(4)-O)(4)(μ-4-R-pyrazolato)(12)X(4)] complexes containing an identical Fe(8)(μ(4)-O)(4) core have been structurally characterized and studied by Mössbauer spectroscopy. In each case, an inner μ(4)-O bridged Fe(III) cubane core is surrounded by four trigonal bipyramidal iron centers, the two distinct sites occurring in a 1:1 ratio. The Mössbauer spectrum of each of the clusters consists of two quadrupole doublets, which, with one exception (X = NCS, R = H), overlap to give three ab...

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Publication status:
Published

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Publisher copy:
10.1021/ic101691q

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Journal:
Inorganic chemistry
Volume:
50
Issue:
3
Pages:
1021-1029
Publication date:
2011-02-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:5bd65fd8-61b4-4ad3-9fe6-7046a982abf3
Source identifiers:
127229
Local pid:
pubs:127229

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