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A first transition series pseudotetrahedral oxynitride anion: synthesis and characterization of Ba(2)VO(3)N.

Abstract:
Ammonolysis of reactive oxide precursors affords the vanadium(V) phase Ba(2)VO(3)N that is shown by X-ray and neutron powder diffraction and Raman spectroscopy to contain pseudotetrahedral VO(3)N(4-) anions. This is the first example of such species for the first transition series metals.
Publication status:
Published

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Publisher copy:
10.1021/ja0122896

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Chalker, PR More by this author
Michie, CW More by this author
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Journal:
Journal of the American Chemical Society
Volume:
124
Issue:
13
Pages:
3337-3342
Publication date:
2002-04-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:5b2a4a87-7928-4424-805c-9dfbc192a13f
Source identifiers:
32079
Local pid:
pubs:32079
Language:
English

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