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Intramolecular base-stabilised adducts of main group halides

Abstract:

The coordination chemistry of alkoxo and amido ligands bearing pendant nitrogen or sulfur donors has been developed to include examples of main group complexes. The structural implications of amido ligand coordination augmented by a tethered pyridyl base have been investigated for group 13 and 14 derivatives {[6-(Me3SiN)-2-Me-C5H3N]SnCl3 and [6-(Me3SiN)-2-Me-C5H3N]BBr2}. Furthermore, the scope, kinetics and mechanism of the synthesis of alkoxo and amido derivatives from trimethylsilyl substit...

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Publication status:
Published

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Publisher copy:
10.1039/b110692a

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Calder, RJ More by this author
Coombs, DL More by this author
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Journal:
NEW JOURNAL OF CHEMISTRY
Volume:
26
Issue:
6
Pages:
677-686
Publication date:
2002
DOI:
EISSN:
1369-9261
ISSN:
1144-0546
URN:
uuid:5b1ad53e-7b47-45d4-878c-641ae0f32954
Source identifiers:
46067
Local pid:
pubs:46067
Language:
English

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