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Prediction and verification of the structural chemistry of new one-dimensional barium/copper/iridium oxides

Abstract:

We propose a classification scheme for the commensurate phases in the family of pseudo one-dimensional structures formed from the mixed hep stacking of A3O9 and oxygen-deficient A3A′O6 layers. We envisage these compounds as composites of two substructures having common a and b unit cell parameters but different parameters c1 and c2. Use of the ratio c1/c2 facilitates the prediction of new commensurate structures while allowing for the commonly incommensurate nature of materials in this family...

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Publication status:
Published

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Publisher copy:
10.1021/cm980317m

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
CHEMISTRY OF MATERIALS
Volume:
10
Issue:
11
Pages:
3536-3547
Publication date:
1998-11-05
DOI:
EISSN:
1520-5002
ISSN:
0897-4756
URN:
uuid:5a9937e0-193f-4c28-a101-112411c4516c
Source identifiers:
36808
Local pid:
pubs:36808
Language:
English

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