- Abstract:
- The syntheses of potassium 2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholide 4 and eta5-pentamethylcyclopentadienyl(eta5-2-(2-methoxynaphth-1-yl)-3,4-dimethyl-5-phenylphospholyl)-ruthenium(II)5 and -iron(II)6 are described. The barrier to rotation of the naphthyl group (79 kJ mol-1 and 72 kJ mol-1 in CD2Cl2 respectively) characterises 5 and 6 as potential tropos type ligands. Coordination of 5 to [PtCl2(PEt3)] gives two cis and two trans complexes [PtCl2(PEt3)5] wherein rotation about the phospholyl-naphthyl vector is slow.
- Publication status:
- Published
- Publisher copy:
- 10.1039/b418926d
-
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- Journal:
- Dalton transactions (Cambridge, England : 2003)
- Issue:
- 12
- Pages:
- 2173-2181
- Publication date:
- 2005-06-05
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
- URN:
-
uuid:5a81097e-695f-443c-a98d-a3f3aa07dc63
- Source identifiers:
-
59856
- Local pid:
- pubs:59856
- Language:
- English
- Copyright date:
- 2005
Journal article
Synthesis, structure and dynamics of methoxynaphthalene-substituted phospha-ruthenocenes and -ferrocenes.
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