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Photoinduced configurational instability at iron in the aminocarbene complexes [(eta(5)-C5H5)Fe(CO)(L){=C(NHR2)(CH2R1)}]+BF4-

Abstract:
Photoinduced epimerisation of chiral iron aminocarbene complexes of the type [(η5-C5H5)Fe(CO)(L)-{=C(NHR 2)(CH2R1)}]+BF4- [L = PPh3, P(p-tolyl)3; R1 = H, Me; R2 = CH2Ph, CH(Me)Ph] has been observed in 10% H2O-MeOH, MeOH, EtOH, THF and CH2Cl2 at room temperature. Exchange experiments have unambiguously established that reversible phosphine ligand (L) dissociation rather than reversible loss of the carbon monoxide ligand is the only mechanism operating.
Publication status:
Published

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Publisher copy:
10.1039/a800937f

Authors


More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Metzler, MR More by this author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
Issue:
5
Pages:
1147-1152
Publication date:
1998-05-05
DOI:
EISSN:
1364-5471
ISSN:
0300-9580
URN:
uuid:5a5be8da-39a7-49c8-a391-de2e151b6511
Source identifiers:
110636
Local pid:
pubs:110636
Language:
English

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