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Studies on the reactivity of group 15 Zintl ions with carbodiimides: synthesis and characterization of a heptaphosphaguanidine dianion.

Abstract:
Reaction of the hydrogenheptaphosphide dianion, [HP(7)](2-), with one equivalent of bis(2,6-diisopropylphenyl)carbodiimide yielded the exo-functionalized cluster [P(7)C(NDipp)(NHDipp)](2-) (Dipp = 2,6-diisopropylphenyl). This species was characterized by single crystal X-ray diffraction, multielement NMR spectroscopy and electrospray mass-spectrometry. DFT calculations on the dianion were also conducted.
Publication status:
Published

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Publisher copy:
10.1039/c1cc12089a

Authors


Turbervill, RS More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Chemical communications (Cambridge, England)
Volume:
48
Issue:
10
Pages:
1470-1472
Publication date:
2012-02-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:5a227835-ed17-47da-95ee-968b8d7a299f
Source identifiers:
154993
Local pid:
pubs:154993

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