Ligand-mediated enantioselective synthesis of acyclic pyrrole carbinols
- The enantioselective synthesis of acyclic pyrrole carbinols via ligand-mediated addition of lithium pyrrolate to aldehydes, and subsequent exploitation of the resulting stereocentre as a stereodirecting group in syn- or anti-selective 1,3-reductions of ketone functionality in the parent aldehyde is described. © Georg Thieme Verlag Stuttgart.
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