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Ligand-mediated enantioselective synthesis of acyclic pyrrole carbinols

Abstract:
The enantioselective synthesis of acyclic pyrrole carbinols via ligand-mediated addition of lithium pyrrolate to aldehydes, and subsequent exploitation of the resulting stereocentre as a stereodirecting group in syn- or anti-selective 1,3-reductions of ketone functionality in the parent aldehyde is described. © Georg Thieme Verlag Stuttgart.
Publication status:
Published

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Publisher copy:
10.1055/s-20054-872698

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
SYNLETT
Issue:
16
Pages:
2420-2424
Publication date:
2005-10-04
DOI:
EISSN:
1437-2096
ISSN:
0936-5214
Source identifiers:
39710
Language:
English
Keywords:
Pubs id:
pubs:39710
UUID:
uuid:59f3f75e-0900-44aa-b04c-ebf07564976b
Local pid:
pubs:39710
Deposit date:
2012-12-19

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