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Electronic origins of structural distortions in post-transition metal oxides: experimental and theoretical evidence for a revision of the lone pair model.

Abstract:

Structural distortions in post-transition metal oxides are often explained in terms of the influence of sp hybrid "lone pairs." Evidence is presented here showing that this model must be revised. The electronic structures of prototypically distorted alpha-PbO and alpha-Bi2O3 have been measured by high-resolution x-ray photoemission and soft x-ray emission spectroscopies. In contrast with the expectations of the lone pair model, a high density of metal 6s states is observed at the bottom of th...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Journal:
Physical Review Letters
Volume:
96
Issue:
15
Pages:
157403
Publication date:
2006-04-01
DOI:
EISSN:
1079-7114
ISSN:
0031-9007
Source identifiers:
39926
Language:
English
Pubs id:
pubs:39926
UUID:
uuid:59d46199-4d16-4bfc-94bd-e9d595d3cb0d
Local pid:
pubs:39926
Deposit date:
2012-12-19

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