- Previously unreported base-induced transformations of rigid bicycloalkene-derived epoxides (4, 8, and 16) are described, providing insight into the rearrangement mechanisms which operate following α-lithiation in such systems.
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Base-induced rearrangements of bicyclo[2.2.1] and bicyclo[2.2.2]alkene-derived epoxides to ketones and alcohols
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