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Journal article

Tuning solute redox potentials by varying the anion component of room temperature ionic liquids.

Abstract:
The electrode potentials for the two one electron oxidations of 1,2-diferrocenylethylene (bisferrocene, BF) were studied relative to that of the one electrode oxidation of decamethylferrocene in a variety of RTILs. The difference in these potentials was found to be very sensitive to the anion component of the ionic liquid showing the scope of these solutes as 'designer media' to tune the thermodynamic properties of solutes dissolved in them.
Publication status:
Published

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Publisher copy:
10.1039/c2cc32308g

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
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Journal:
Chemical communications (Cambridge, England)
Volume:
48
Issue:
46
Pages:
5784-5786
Publication date:
2012-06-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:59225bce-d2b0-4626-99b1-aab1a1908e0d
Source identifiers:
329006
Local pid:
pubs:329006
Language:
English

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