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On the microstructure and symmetry of apparently hexagonal BaAl2O4

Abstract:

The P63 (a=2ap, b=2bp, c=cp) crystal structure reported for BaAl2O4 at room temperature has been carefully re-investigated by a combined transmission electron microscopy and neutron powder diffraction study. It is shown that the poor fit of this P63 (a=2ap, b=2bp, c=cp) structure model for BaAl2O4 to neutron powder diffraction data is primarily due to the failure to take into account coherent scattering between different domains related by enantiomorphic twinning of the P6322 parent sub-struc...

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Publisher copy:
10.1016/j.jssc.2008.03.043

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
Journal of Solid State Chemistry
Volume:
181
Issue:
8
Pages:
1816-1823
Publication date:
2008-08-05
DOI:
EISSN:
1095-726X
ISSN:
0022-4596
URN:
uuid:591b95b7-67f9-4494-aa26-dc415c5d9b70
Source identifiers:
292546
Local pid:
pubs:292546

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