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Polymethylaluminoxane supported zirconocene catalysts for polymerisation of ethylene

Abstract:

We report here the synthesis of two new ansa-bridged permethylindenyl zirconocenes, their reaction with solid polymethylaluminoxane (sMAO) and their use in slurry phase ethylene polymerisation. Meso-(EBI*)Zr(CH2Ph)2 and meso-(EBI*)Zr(CH2tBu)Cl, (EBI* = ethylenebis[1-(2,3,4,5,6,7-hexamethylindenyl)]) were synthesised from meso-(EBI*)ZrCl2 and KCH2Ph and LiCH2tBu respectively. The new zirconocenes were characterised by NMR spectroscopy and X-ray crystallography, and density functional theory ca...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Publisher copy:
10.1016/j.jorganchem.2016.08.015

Authors


Arnold, TAQ More by this author
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Department:
Balliol College
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Funding agency for:
Turner, ZR
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Funding agency for:
Turner, ZR
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Funding agency for:
Buffet, J-C
Publisher:
Elsevier Publisher's website
Journal:
Journal of Organometallic Chemistry Journal website
Volume:
822
Pages:
85-90
Publication date:
2016-08-05
Acceptance date:
2016-08-16
DOI:
ISSN:
0022-328X
Pubs id:
pubs:642084
URN:
uri:5916867a-09fe-40b9-a68b-439b2d17d5c8
UUID:
uuid:5916867a-09fe-40b9-a68b-439b2d17d5c8
Local pid:
pubs:642084

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