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Polynuclear lanthanide complexes of a series of bridging ligands containing two tridentate N,N',O-donor units: structures and luminescence properties.

Abstract:

A set of three potentially bridging ligands containing two tridentate chelating N,N',O-donor (pyrazole-pyridine-amide) donors separated by an o, m, or p-phenylene spacer has been prepared and their coordination chemistry with lanthanide(III) ions investigated. Ligand L(1) (p-phenylene spacer) forms complexes with a 2:3 M:L ratio according to the proportions used in the reaction mixture; the Ln(2)(L(1))(3) complexes contain two 9-coordinate Ln(III) centres with all three bridging ligands spann...

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Publication status:
Published

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Publisher copy:
10.1039/b618258e

Authors


Ronson, TK More by this author
Harding, LP More by this author
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Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
10
Pages:
1006-1022
Publication date:
2007-03-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:588576a5-3175-43d7-868d-10c2da2e35b6
Source identifiers:
46789
Local pid:
pubs:46789
Language:
English

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