- Abstract:
- The asymmetric synthesis of (-)-lupinine was achieved in 8 steps, 15% overall yield and >99 : 1 dr from commercially available starting materials. The strategy used for the construction of the quinolizidine scaffold involved reaction of an enantiopure tertiary dibenzylamine via two sequential ring-closures which both occurred with concomitant N-debenzylation.
- Publication status:
- Published
- Publisher copy:
- 10.1039/c4cc02135e
-
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- Publisher:
- Royal Society of Chemistry
- Journal:
- Chemical communications (Cambridge, England)
- Volume:
- 50
- Issue:
- 61
- Pages:
- 8309-8311
- Publication date:
- 2014-08-05
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- URN:
-
uuid:57f73666-38a4-4ec8-a5b5-e09a6f238d2d
- Source identifiers:
-
471119
- Local pid:
- pubs:471119
- Language:
- English
- Copyright date:
- 2014
Journal article
An efficient asymmetric synthesis of (-)-lupinine.
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