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Nitrate anion templated assembly of a [2]rotaxane for selective nitrate recognition in aqueous solvent mixtures.

Abstract:
The first nitrate anion templated assembly of an interlocked molecular architecture is demonstrated through the preparation of a [2]rotaxane. Removal of the discrete nitrate anion template from the [2]rotaxane reveals an interlocked host system capable of strong and selective recognition of nitrate, in aqueous-organic solvent mixtures, over a range of more basic mono-charged oxoanions.
Publication status:
Published

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Publisher copy:
10.1039/c3cc45342a

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Chemical communications (Cambridge, England)
Volume:
49
Issue:
77
Pages:
8608-8610
Publication date:
2013-10-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:5759cfca-31cd-489f-b4e1-d923f6d7faa9
Source identifiers:
418537
Local pid:
pubs:418537
Language:
English

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