- The first nitrate anion templated assembly of an interlocked molecular architecture is demonstrated through the preparation of a rotaxane. Removal of the discrete nitrate anion template from the rotaxane reveals an interlocked host system capable of strong and selective recognition of nitrate, in aqueous-organic solvent mixtures, over a range of more basic mono-charged oxoanions.
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Nitrate anion templated assembly of a rotaxane for selective nitrate recognition in aqueous solvent mixtures.
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