Journal article
Temperature dependence of OH yield, translational energy, and vibrational branching in the reaction of O(3P)(g) with liquid squalane
- Abstract:
-
The relative reactivity of the liquid surface of a long-chain, partially branched hydrocarbon (squalane, C30H62) with gas-phase O(3P) atoms has been measured as a function of liquid temperature. The O(3P) atoms were generated with a superthermal velocity distribution by 355 nm photolysis of NO2. Laser-induced fluorescence was used to detect the relative branching into specific OH product vibrational states. The yield of OH(v′=0) proves significantly less dependent on liquid surface temperatur...
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- Publisher copy:
- 10.1021/jp074147p
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Bibliographic Details
- Journal:
- Journal of Physical Chemistry C
- Volume:
- 111
- Issue:
- 40
- Pages:
- 14833-14842
- Publication date:
- 2007-10-11
- DOI:
- EISSN:
-
1932-7455
- ISSN:
-
1932-7447
- Source identifiers:
-
288849
Item Description
- Language:
- English
- Pubs id:
-
pubs:288849
- UUID:
-
uuid:5759131d-0f0d-4101-989c-9ff5f0e50eee
- Local pid:
- pubs:288849
- Deposit date:
- 2013-11-17
Terms of use
- Copyright date:
- 2007
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