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Temperature dependence of OH yield, translational energy, and vibrational branching in the reaction of O(3P)(g) with liquid squalane

Abstract:

The relative reactivity of the liquid surface of a long-chain, partially branched hydrocarbon (squalane, C30H62) with gas-phase O(3P) atoms has been measured as a function of liquid temperature. The O(3P) atoms were generated with a superthermal velocity distribution by 355 nm photolysis of NO2. Laser-induced fluorescence was used to detect the relative branching into specific OH product vibrational states. The yield of OH(v′=0) proves significantly less dependent on liquid surface temperatur...

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Publisher copy:
10.1021/jp074147p

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Institution:
University of Oxford
Department:
Oxford, MPLS, Materials
Role:
Author
Journal:
Journal of Physical Chemistry C
Volume:
111
Issue:
40
Pages:
14833-14842
Publication date:
2007-10-11
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
URN:
uuid:5759131d-0f0d-4101-989c-9ff5f0e50eee
Source identifiers:
288849
Local pid:
pubs:288849
Language:
English

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