Journal article

[Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex.

Abstract:: Reaction of [Ir(PPh(3))(2)(COD)][BAr(F)(4)] with H(2) in dichloroethane solution results in [Ir(PPh(3))(2)(H)(2)(ClCH(2)CH(2)Cl)][BAr(F)(4)], which has been fully characterised by X-ray crystallography, NMR spectroscopy and ESI-MS. Its activity towards alkene hydrogenation has been compared with analogous CH(2)Cl(2) complexes.

Publication status:: Published

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APA Style

Moxham, G., Brayshaw, S., & Weller, A. (2007). [Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex. Dalton Transactions (Cambridge, England : 2003), 18, 1759–1761.

MLA Style

Moxham, G., et al. “[Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a Well Characterised Transition Metal Dichloroethane Complex.” Dalton Transactions (Cambridge, England : 2003), no. 18, 2007, pp. 1759–61.

Chicago Style

Moxham, G, S Brayshaw, and A Weller. 2007. “[Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a Well Characterised Transition Metal Dichloroethane Complex.” Dalton Transactions (Cambridge, England : 2003), no. 18: 1759–61.
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Publisher copy:: 10.1039/b702399e

Authors

+ Moxham, G More by this author

Role:: Author

+ Brayshaw, S More by this author

Role:: Author

+ Weller, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: Dalton transactions (Cambridge, England : 2003) More from this journal
Issue:: 18
Pages:: 1759-1761
Publication date:: 2007-05-01
DOI:: 10.1039/b702399e
EISSN:: 1477-9234
ISSN:: 1477-9226

Language:: English
Keywords:: Models, Molecular

Crystallography, X-Ray

Organometallic Compounds

Molecular Structure

Metals

Ethylene Dichlorides

Hydrogen
Pubs id:: pubs:51698
UUID:: uuid:5729cf8b-64e3-4782-b80c-e3f2ba9e0ee8
Local pid:: pubs:51698
Source identifiers:: 51698
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2007

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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