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Exploration of composition space in templated uranium sulfates.

Abstract:

The phase stability of organically templated uranium sulfates in the [UO(2)(CH(3)CO(2))(2).2H(2)O/homopiperazine/H(2)SO(4)] and [UO(2)(CH(3)CO(2))(2).2H(2)O/N,N-dimethylethylenediamine/H(2)SO(4)] systems has been studied using composition space. Two new compounds were formed in each system; [N(2)C(5)H(14)](2)[UO(2)(SO(4))(3)] (USO-17) and [N(2)C(5)H(14)][UO(2)(H(2)O)(SO(4))(2)] (USO-18) contain homopiperazine, and [N(2)C(4)H(14)][UO(2)(SO(4))(2)] (USO-19) and [N(2)C(4)H(14)][(UO(2))(2)(H(2)O)...

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Publication status:
Published

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Publisher copy:
10.1021/ic034540j

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry
Volume:
42
Issue:
22
Pages:
6989-6995
Publication date:
2003-11-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:571adafc-b133-4b01-8a52-a4174e909247
Source identifiers:
51192
Local pid:
pubs:51192
Language:
English

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