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Structural chemistry and magnetic properties of incommensurate Sr1+x(CoxMn1-x)O-3

Abstract:

The incommensurate, modulated crystal structures of Sr 1+x(CoxMn1-x)O3 (x ≈ 0.266 and 0.280) have been refined by a (3+1)D superspace profile analysis of neutron powder diffraction data. The structures are related to the 2H perovskite structure and consist of two subsystems, [CoxMn1-xO 3]∞ chains containing face-sharing MnO6 octahedra and CoO6 trigonal prisms (albeit with some cation site inversion), separated from each other by [Sr]∞ chains. The observed structures are closely related to tho...

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Publication status:
Published

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Publisher copy:
10.1021/cm031096+

Authors


Jordan, NA More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
van Smaalen, S More by this author
Wunschel, M More by this author
Journal:
CHEMISTRY OF MATERIALS
Volume:
15
Issue:
22
Pages:
4262-4267
Publication date:
2003-11-04
DOI:
EISSN:
1520-5002
ISSN:
0897-4756
URN:
uuid:56cf3c84-2e5f-46e2-857a-60f3e24be591
Source identifiers:
38812
Local pid:
pubs:38812
Language:
English

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