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Straightforward synthesis of alpha,beta-epoxysilanes from terminal epoxides by lithium 2,2,6,6-tetramethylpiperidide-mediated deprotonation-in situ silylation

Abstract:
Lithiation-in situ silylation of simple terminal epoxides using lithium 2,2,6,6-tetramethylpiperidide in combination with trimethylsilyl chloride provides a direct and experimentally convenient process for the synthesis of trans-α,β-epoxysilanes. © 2002 Elsevier Science Ltd. All rights reserved.
Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
Journal:
TETRAHEDRON LETTERS
Volume:
43
Issue:
44
Pages:
7895-7897
Publication date:
2002-10-28
DOI:
ISSN:
0040-4039
URN:
uuid:56af86db-8722-4484-ab9c-5884cfa92fb7
Source identifiers:
38410
Local pid:
pubs:38410
Language:
English
Keywords:

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