The multichannel-quantum-defect theory (MQDT) of the Stark effect is applied to the simulation of transitions in molecular hydrogen to the autoionizing Rydberg states in the region between the v+=1 and v+=2 thresholds, with principal quantum numbers 13-19, for applied electric fields in the range 100-1300 V/cm. The vibrational coupling between Rydberg states belonging to different series is included for the first time in a MQDT Stark-effect calculation. The results of the calculations are com...Expand abstract
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Multichannel-quantum-defect-theory analysis of the Stark effect in autoionizing Rydberg states of H2.
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