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Synthesis and reactivity of transition metal complexes containing halogenated boryl ligands

Abstract:
The synthesis and characterization of iron and manganese complexes containing the tetrachlorocatecholboryl (BO2C6Cl4) ligand are reported. Crystallographic study of the methylcyclopentadienyl derivative and reveals that the relative orientation of (η5-C5H4Me)Fe(CO)2 and BO2C6Cl4 moieties is influenced by intramolecular C-H(triple dot sign)O hydrogen bonding. Additionally, an alternative route to catecholboryl complexes from dilithiocatechol is reported. © 2002 Elsevier Science B.V. All rights reserved.
Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume:
649
Issue:
1-2
Pages:
9-14
Publication date:
2002-04-15
DOI:
ISSN:
0022-328X
URN:
uuid:562653de-998d-454f-b402-16e9be6e7d84
Source identifiers:
46069
Local pid:
pubs:46069
Language:
English
Keywords:

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