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Quantitative Voltammetry in Weakly Supported Media. Two Electron Transfer, Chronoamperometry of Electrodeposition and Stripping for Cadmium at Microhemispherical Mercury Electrodes

Abstract:

Double potential step chronoamperometry for the two-electron transfer amalgam-forming deposition and stripping of cadmium at a hemispherical mercury electrode in aqueous solution containing different concentrations of supporting electrolyte is compared with simulated results using the Nernst-Planck-Poisson system of equations. The latter were generated using an approximation of zero electric field at the interface [J. Phys. Chem. C 2008, 112, 13716-13728]; the approximation gives a good agree...

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Publication status:
Published

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Publisher copy:
10.1021/jp9047314

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY C
Volume:
113
Issue:
34
Pages:
15320-15325
Publication date:
2009-08-27
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
URN:
uuid:55ca835b-80d8-4c64-8fe0-19e93cadf9b6
Source identifiers:
41363
Local pid:
pubs:41363
Language:
English

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