- Abstract:
- The efficient synthesis of a D-galacto-configured tetrahydrofuran amino acid from a seven-carbon lactone as a monomer for the generation of sequence-defined structured biopolymer mimics is described. Investigations into the characteristics of homooligomeric derivatives of this monomer indicate that they do not adopt well defined secondary structures. The unanticipated formation of a heterooligomeric derivative and investigations into its solution structure are also described. © The Royal Society of Chemistry 2000.
- Publication status:
- Published
- Publisher copy:
- 10.1039/b002995p
-
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- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
- Issue:
- 21
- Pages:
- 3655-3665
- Publication date:
- 2000-01-01
- DOI:
- EISSN:
-
1364-5463
- ISSN:
-
1470-4358
- URN:
-
uuid:555d6241-774a-47f0-adf8-c911cbd3282d
- Source identifiers:
-
37587
- Local pid:
- pubs:37587
- Language:
- English
- Copyright date:
- 2000
Journal article
Tetrahydrofuran amino acids - versatile building blocks for unnatural biopolymers: lack of secondary structure in oligomeric carbopeptoids derived from a D-galacto-5-(aminomethyl) tetrahydrofuran-2-carboxylic acid
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