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Multichannel-quantum-defect-theory analysis of the Stark effect in autoionizing Rydberg states of H2

Abstract:

The multichannel-quantum-defect theory (MQDT) of the Stark effect is applied to the simulation of transitions in molecular hydrogen to the autoionizing Rydberg states in the region between the v^(+) = 1 and v^(+) = 2 thresholds, with principal quantum numbers 13-19, for applied electric fields in the range 100-1300 V/cm. The vibrational coupling between Rydberg states belonging to different series is included for the first time in a MQDT Stark-effect calculation. The results of the calculatio...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

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Publisher copy:
10.1103/PhysRevA.49.969

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Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Physical and Theoretical Chemistry Laboratory
More by this author
Institution:
University of Oxford
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Physical and Theoretical Chemistry Laboratory
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Funding agency for:
H. H. Fielding
Publisher:
American Physical Society Publisher's website
Journal:
Physical Review A Journal website
Volume:
49
Issue:
2
Pages:
969-981
Publication date:
1994-02-05
DOI:
EISSN:
1094-1622
ISSN:
1050-2947
URN:
uuid:551ad71c-ba6d-41a1-a785-2637e3f10896
Local pid:
ora:2899

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