Oxidation of anthracene on platinum macro- and micro-electrodes: Sonoelectrochemical, cryoelectrochemical and sonocryoelectrochemical studies.
The electro- and sonoelectro-chemical oxidation of anthracene in acetonitrile has been explored at room and low temperature (-40 degrees C) at a platinum micro- and macro-electrode, respectively. From both methodologies, the effective number of electrons, n(eff), in the oxidation process is evaluated at both room temperature and at the limit of the solvent-electrolyte freezing point. It is observed that n(eff) is close to 1 at low temperature while at room temperature it is higher, indicating...Expand abstract
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