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INFRARED MULTIPLE-PHOTON DISSOCIATION AS A SOURCE OF REACTIVE FREE-RADICALS - METHYLENE REVISITED

Abstract:
Rate constants for collisional removal of ã1 A 1 CH2 and CD2 have been directly measured for the first time, by using IR multiplephoton dissociation to produce the radicals and time-resolved laser-induced fluorescence to detect them. Contributions to the removal processes from both intersystem crossing and chemical reaction are discussed. © 1981 Società Italiana di Fisica.
Publication status:
Published

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Publisher copy:
10.1007/BF02721408

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Publisher:
Società Italiana di Fisica
Journal:
NUOVO CIMENTO DELLA SOCIETA ITALIANA DI FISICA B-GENERAL PHYSICS RELATIVITY ASTRONOMY AND MATHEMATICAL PHYSICS AND METHODS
Volume:
63
Issue:
1
Pages:
28-35
Publication date:
1981-01-01
DOI:
EISSN:
1826-9877
ISSN:
0369-3554
URN:
uuid:5466eed2-0f3e-4dda-a7e9-ad4c1cf61671
Source identifiers:
42001
Local pid:
pubs:42001
Language:
English

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