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Novel (n + 1 + 1) cycloaddition reactions; the formation of cyclic tetraphosphonium dications with four linked phosphorus atoms and an organic backbone.

Abstract:
In the presence of SnCl(2), a novel cycloaddition of two moles of R'PCl(2) (R' = Et or Ph) to a diphosphane has been achieved, forming a cyclic dication with four linked phosphorus atoms and an organic backbone; two of these species have been characterised by single-crystal X-ray diffraction, and the mechanism of the reaction has been established.
Publication status:
Published

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Publisher copy:
10.1039/b618157k

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
14
Pages:
1374-1376
Publication date:
2007-04-01
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
Source identifiers:
117132
Language:
English
Keywords:
Pubs id:
pubs:117132
UUID:
uuid:53d0c738-7477-4b08-9d26-6b46aa1f0a45
Local pid:
pubs:117132
Deposit date:
2012-12-19

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