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Synthesis and characterization of ternary clusters containing the [As16]10– anion, [MM'As16]4– (M = Nb or Ta; M' = Cu or Ag)

Abstract:

The [Nb@As8]3– anion was first isolated from solution in 1986, and a number of isostructural [M@Pn8]n clusters (M = Nb, Cr, or Mo; Pn = As or Sb; n = 2 or 3) have since been reported. We show here how anions of this class can be used as synthetic precursors that, in combination with sources of low-valent late transition metals (Cu and Ag), generate ternary polyarsenide cluster anions with unprece...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.inorgchem.1c03940

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Role:
Author
ORCID:
0000-0001-6482-3223
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Role:
Author
ORCID:
0000-0001-9647-8807
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Role:
Author
ORCID:
0000-0001-7407-3446
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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
New College
Role:
Author
ORCID:
0000-0002-8991-1921
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Role:
Author
ORCID:
0000-0003-2894-6327
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Name:
National Natural Science Foundation of China
Publisher:
American Chemical Society
Journal:
Inorganic Chemistry More from this journal
Volume:
61
Issue:
10
Pages:
4421-4427
Publication date:
2022-03-01
Acceptance date:
2022-03-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Pmid:
35230830
Language:
English
Keywords:
Pubs id:
1243157
Local pid:
pubs:1243157
Deposit date:
2023-01-15

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