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Heterogeneous or homogeneous? A case study involving palladium-containing perovskites in the Suzuki reaction

Abstract:
The utility of a series of palladium-containing perovskite catalysts in the Suzuki reaction is described; turnover numbers of up to 400,000 are reported. A detailed investigation into the mode of action of these catalysts encompassing kinetic studies, catalyst poisoning, microscopy and three-phase tests demonstrate that these heterogeneous materials are pre-catalysts that operate by a solution-phase mechanism. © 2005 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/adsc.200404331

Authors


Andrews, SP More by this author
Stepan, AF More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Journal:
ADVANCED SYNTHESIS and CATALYSIS
Volume:
347
Issue:
5
Pages:
647-654
Publication date:
2005-04-05
DOI:
EISSN:
1615-4169
ISSN:
1615-4150
URN:
uuid:526a5ad0-e467-469a-a1e7-c8c16ca04737
Source identifiers:
58769
Local pid:
pubs:58769

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