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Thermal, pressure and light induced spin transition in the two-dimensional coordination polymer [Fe(pmd)2[Cu(CN)2]2].

Abstract:

A complete structural, calorimetric, and magnetic characterisation of the 2D coordination spin crossover polymer [Fe(pmd)(2)[Cu(CN)(2)](2)] is reported. The crystal structure has been investigated below room temperature at 180 K and 90 K, and at 30 K after irradiating the sample at low temperature with green light (lambda = 532 nm). The volume cell contraction through the thermal spin transition is only 18 A(3) which is lower than the usually observed value of around 25-30 A(3) while the aver...

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Publication status:
Published

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Publisher copy:
10.1039/b711834a

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
Dalton transactions (Cambridge, England : 2003)
Issue:
5
Pages:
642-649
Publication date:
2008-02-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:523d41cd-3e82-4f9a-a87d-e17f198727f3
Source identifiers:
117188
Local pid:
pubs:117188
Language:
English

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