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Hydrogen-bonding motifs in the solid-state structure of ferroceneboronic acid

Abstract:

At 180 K, the crystal structure of ferroceneboronic acid, [Fe(C 5H5)(C5H6BO2)], consists of centrosymmetric [FcB(OH)2]2 dimers [Fc is (η5-C5H5)Fe(η5-C 5H4)], formed by a pair of complementary O-H⋯O hydrogen-bonding interactions [O⋯H 1.97 Å and O⋯O 2.806 (3) Å]. The remaining two O-bound H atoms per [FcB(OH)2] 2 moiety serve to link the dimeric units to adjacent dimers in a criss-cross fashion, very similar to that between hydrogen-bonded chains in solid Fe[η5-C5H4B(OH)2] 2. © 2004 Internation...

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Publication status:
Published

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Publisher copy:
10.1107/S1600536804006014

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Volume:
60
Issue:
4
Pages:
M441-M443
Publication date:
2004-04-05
DOI:
EISSN:
1600-5368
ISSN:
1600-5368
URN:
uuid:519cf15f-032a-43f3-8469-4569e9875fa0
Source identifiers:
46058
Local pid:
pubs:46058
Language:
English

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