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Hydrodynamic voltammetry with channel microband electrodes: Axial diffusion effects

Abstract:
The strongly implicit procedure is used to simulate the response of channel electrodes under conditions where diffusional effects in the direction (axis) of solution flow are significant. The cases of flow rate dependence of the steady-state transport limited current, potential step transients and ECE processes are considered and the conditions identified under which axial diffusion effects are considerable.
Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
404
Issue:
1
Pages:
27-35
Publication date:
1996-03-07
DOI:
ISSN:
1572-6657
URN:
uuid:51228bd9-52db-4216-8c32-507c5abc0d87
Source identifiers:
45160
Local pid:
pubs:45160

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