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Journal article

Enzyme electrokinetics: electrochemical studies of the anaerobic interconversions between active and inactive states of Allochromatium vinosum [NiFe]-hydrogenase.

Abstract:

The cycling between active and inactive states of the catalytic center of [NiFe]-hydrogenase from Allochromatium vinosum has been investigated by dynamic electrochemical techniques. Adsorbed on a rotating disk pyrolytic graphite "edge" electrode, the enzyme is highly electroactive: this allows precise manipulations of the complex redox chemistry and facilitates quantitative measurements of the interconversions between active catalytic states and the inactive oxidized form Ni(r) (also called N...

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Publication status:
Published

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Publisher copy:
10.1021/ja035296y

Authors


Pershad, HR More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Albracht, SP More by this author
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Journal:
Journal of the American Chemical Society
Volume:
125
Issue:
28
Pages:
8505-8514
Publication date:
2003-07-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:51185fcd-fb58-421a-b7e6-ba9adbb26812
Source identifiers:
32404
Local pid:
pubs:32404

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