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Imparting pH- and small molecule selectivity to nano-Pd catalysts via hydrothermal wrapping with chitosan

Abstract:

A nano-composite of negatively charged carbon nanoparticles (Emperor 2000™), chitosan, and nano-palladium is produced in a one-step hydrothermal process with oxalate reductant. In voltammetric measurements strong pH effects on capacitance and Faradaic current responses are observed due to chitosan forming a shell (or "hydrothermal wrapping") around both carbon nanoparticles and palladium particles in the water-based hydrothermal process. In spite of the wrapping, some Pd-catalytic processes a...

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Publication status:
Published

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Journal:
ELECTROCHIMICA ACTA
Volume:
110
Pages:
663-669
Publication date:
2013-11-01
DOI:
ISSN:
0013-4686
URN:
uuid:5090dc90-2daa-4f5d-8067-eb2ffcc4fdef
Source identifiers:
384729
Local pid:
pubs:384729

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