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Mg/O2 battery based on the magnesium–aluminum chloride complex (MACC) electrolyte

Abstract:

Mg/O2 cells employing a MgCl2/AlCl3/DME (MACC/DME) electrolyte are cycled and compared to cells with modified Grignard electrolytes, showing that performance of magnesium/oxygen batteries depends strongly on electrolyte composition. Discharge capacity is far greater for MACC/DME-based cells, while rechargeability in these systems is severely limited. The Mg/O2-MACC/DME discharge product comprises a mixture of Mg(ClO4)2 and MgCl2, with the latter likely formed from slow decomposition of the fo...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1021/acs.chemmater.6b02488

Authors


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DENSO International America, Inc. More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Chemistry of Materials Journal website
Volume:
28
Issue:
21
Pages:
7629-7637
Publication date:
2016-11-08
DOI:
EISSN:
1520-5002
ISSN:
0897-4756
Pubs id:
pubs:661187
URN:
uri:50128f2d-9563-4676-9cb4-be36455460ba
UUID:
uuid:50128f2d-9563-4676-9cb4-be36455460ba
Local pid:
pubs:661187
Paper number:
21
Keywords:

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