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Conformer specific dissociation dynamics of iodocyclohexane studied by velocity map imaging.

Abstract:

The photodissociation dynamics of iodocyclohexane has been studied using velocity map imaging following excitation at many wavelengths within its A-band (230 ≤ λ ≤ 305 nm). This molecule exists in two conformations (axial and equatorial), and one aim of the present experiment was to explore the extent to which conformer-specific fragmentation dynamics could be distinguished. Ground (I) and spin-orbit excited (I∗) state iodine atom products were monitored by 2 + 1 resonance enhanced multiphoto...

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Publication status:
Published

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Publisher copy:
10.1063/1.3628682

Authors


Zaouris, DK More by this author
Murdock, D More by this author
Oliver, TA More by this author
Richmond, G More by this author
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Journal:
The Journal of chemical physics
Volume:
135
Issue:
9
Pages:
094312
Publication date:
2011-09-05
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
URN:
uuid:4fa54b7a-6296-4fae-bda2-b0a02e94b3c7
Source identifiers:
177289
Local pid:
pubs:177289
Language:
English

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