ELECTRONIC-SPECTRUM OF THE AR-OH COMPLEX - EFFECT OF ISOTOPIC-SUBSTITUTION AND TEMPERATURE
- The spectrum of ArOD in the region of the OD (A 2Σ+, v=0) ← OD (X 2Π, v=0) electronic transition has been calculated at a temperature of 1.7 K using an ab initio potential energy surface. The calculated line positions, vibrational spacings and rotor constants are compared with experiment. The ArOH and ArOD spectra are also calculated at a temperature of 20 K and the hot band structure of the spectrum is discussed. © 1990.
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