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Electrochemical insertion of Li into Sr2MO2Cu 2S2 (M = Mn, Co, Ni)

Abstract:

The layered oxysulfides Sr2AZO2Cu2S 2 (M = Mn, Co, Ni) consist of alternating perovskite-type Sr 2AZO2 layers and copper sulfide layers. We studied the electrochemical insertion of Li into these three samples. By this we were able to study the influence of the nature of the transition metal on the Li insertion process which appears to be at least partially reversible. While the Mn compound clearly shows a Cu-Li exchange reaction, the electrochemical process for the two other compounds is more...

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Journal:
Materials Research Society Symposium Proceedings
Volume:
988
Pages:
80-85
Publication date:
2006-01-01
ISSN:
0272-9172
URN:
uuid:4f577936-dcc8-4e7d-a3fa-d3cc95356590
Source identifiers:
192192
Local pid:
pubs:192192
Language:
English

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