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Ferromagnetism in the filled beta-Mn phase Fe2-xRhxMo3N

Abstract:

Compositions in the solid solution Fe2-xRhxMo 3N which adopt the filled β-manganese structure have been prepared by the reductive nitridation of mixed binary metal oxides; single-phase samples can be prepared for 0.3 ≤ x ≤ 0.75. Those compositions with x ≤ 1 have been shown, by a combination of magnetometry, neutron diffraction and μSR, to be ferromagnetic at low temperatures. The Curie temperature is highest (Tc = 110 K) for x = 0.5, with a saturation magnetisation of 2.26(1) μB per formula ...

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Publication status:
Published

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Publisher copy:
10.1039/b505221a

Authors


Oldham, SE More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Institution:
University of Oxford
Department:
Oxford, MPLS, Physics, Condensed Matter Physics
Brooks, ML More by this author
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Journal:
JOURNAL OF MATERIALS CHEMISTRY
Volume:
15
Issue:
33
Pages:
3402-3408
Publication date:
2005
DOI:
EISSN:
1364-5501
ISSN:
0959-9428
URN:
uuid:4e1892fd-320d-455b-9166-4d6e16445c20
Source identifiers:
18410
Local pid:
pubs:18410
Language:
English

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