- Abstract:
-
Compositions in the solid solution Fe2-xRhxMo 3N which adopt the filled β-manganese structure have been prepared by the reductive nitridation of mixed binary metal oxides; single-phase samples can be prepared for 0.3 ≤ x ≤ 0.75. Those compositions with x ≤ 1 have been shown, by a combination of magnetometry, neutron diffraction and μSR, to be ferromagnetic at low temperatures. The Curie temperature is highest (Tc = 110 K) for x = 0.5, with a saturation magnetisation of 2.26(1) μB per formula ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/b505221a
-
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- Journal:
- JOURNAL OF MATERIALS CHEMISTRY
- Volume:
- 15
- Issue:
- 33
- Pages:
- 3402-3408
- Publication date:
- 2005
- DOI:
- EISSN:
-
1364-5501
- ISSN:
-
0959-9428
- URN:
-
uuid:4e1892fd-320d-455b-9166-4d6e16445c20
- Source identifiers:
-
18410
- Local pid:
- pubs:18410
- Language:
- English
- Copyright date:
- 2005
Journal article
Ferromagnetism in the filled beta-Mn phase Fe2-xRhxMo3N
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