The complexes and contain [M(bipy)(3)](2+) chromophores with a pendant aza-18-crown-6 macrocycle for binding of lanthanide(iii) ions. The photophysical properties of the adducts . and ., prepared by addition of excess Ln(NO(3))(3) (Ln = Nd, Yb) to solutions of and in MeCN, were examined using time-resolved and steady-state luminescence methods. Whereas does not act as an energy-donor to Yb(iii), it will transfer energy to (and generate sensitised near-infrared luminescence from) Nd(iii) with ...Expand abstract
- Publication status:
- Publisher copy:
- Copyright date:
[Ru(bipy)(3)](2+) and [Os(bipy)(3)](2+) chromophores as sensitisers for near-infrared luminescence from Yb(iii) and Nd(iii) in d/f dyads: contributions from Forster, Dexter, and redox-based energy-transfer mechanisms.
Views and Downloads
If you are the owner of this record, you can report an update to it here: Report update to this record