- Abstract:
-
The complexes and contain [M(bipy)(3)](2+) chromophores with a pendant aza-18-crown-6 macrocycle for binding of lanthanide(iii) ions. The photophysical properties of the adducts . and ., prepared by addition of excess Ln(NO(3))(3) (Ln = Nd, Yb) to solutions of and in MeCN, were examined using time-resolved and steady-state luminescence methods. Whereas does not act as an energy-donor to Yb(iii), it will transfer energy to (and generate sensitised near-infrared luminescence from) Nd(iii) with ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1039/b901560d
-
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- Journal:
- Dalton transactions (Cambridge, England : 2003)
- Issue:
- 20
- Pages:
- 3971-3979
- Publication date:
- 2009-05-05
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
- URN:
-
uuid:4bb6cfef-ab77-4bd7-b009-8cd4253cded8
- Source identifiers:
-
46779
- Local pid:
- pubs:46779
- Language:
- English
- Copyright date:
- 2009
Journal article
[Ru(bipy)(3)](2+) and [Os(bipy)(3)](2+) chromophores as sensitisers for near-infrared luminescence from Yb(iii) and Nd(iii) in d/f dyads: contributions from Forster, Dexter, and redox-based energy-transfer mechanisms.
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