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In situ X-ray powder diffraction studies of hydrogen storage and release in the Li-N-H system

Abstract:

We report the experimental investigation of hydrogen storage and release in the lithium amide-lithium hydride composite (Li-N-H) system. Investigation of hydrogenation and dehydrogenation reactions of the system through in situ synchrotron X-ray powder diffraction experiments allowed for the observation of the formation and evolution of non-stoichiometric intermediate species of the form Li1+xNH2-x. This result is consistent with the proposed Frenkel-defect mechanism for these reactions. We o...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c4cp00087k

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Institution:
University of Oxford
Department:
Oxford
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Publisher:
Royal Society of Chemistry
Journal:
Physical chemistry chemical physics: PCCP More from this journal
Volume:
16
Issue:
9
Pages:
4061-4070
Publication date:
2014-01-13
Acceptance date:
2014-01-13
DOI:
EISSN:
1463-9084
ISSN:
1463-9076
Language:
English
Keywords:
Pubs id:
pubs:446803
UUID:
uuid:4b7585e2-7b05-494e-99f6-4a139d38b87e
Local pid:
pubs:446803
Source identifiers:
446803
Deposit date:
2014-06-11

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