Journal article icon

Journal article

ELECTRON-SPIN RESONANCE-SPECTRA OF SOLVATED ALKALI-METAL ATOMS IN FROZEN SOLUTIONS OF SODIUM, POTASSIUM, RUBIDIUM, AND CESIUM IN HEXAMETHYLPHOSPHORAMIDE

Abstract:

Low temperature glasses formed by rapid freezing of potassium-, rubidium-, and caesium-hexamethylphosphoramide (HMPA) solutions gave electron spin resonance (ESR) spectra which consisted of a central singlet (Gaussian) resonance and a multiplet of lines characteristic of hyperfine coupling to a single metal nucleus. The species giving rise to the resolved metal hyperfine coupling have been identified as solvated alkalimetal atoms with metal ns orbital occupation in the range 60-70% of the fre...

Expand abstract
Publication status:
Published

Actions


Access Document


Authors


Journal:
ADVANCES IN MOLECULAR RELAXATION AND INTERACTION PROCESSES
Volume:
13
Issue:
2
Pages:
123-169
Publication date:
1978-01-01
DOI:
ISSN:
0378-4487
URN:
uuid:4b5fdb8f-1aeb-490e-b710-22c53c8f646c
Source identifiers:
46441
Local pid:
pubs:46441
Language:
English

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP