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SYNTHESIS AND STRUCTURE OF CA6MNN5 - A NEW NITRIDOMANGANATE WITH PLANAR [MNN3](6-)ANIONS

Abstract:

The new ternary nitride Ca6MnN5 has been synthesized by the solid state reaction of Ca3N2 with Mn4N and characterized by powder X-ray diffraction. Ca6MnN5 crystallizes in the hexagonal space group P63/mcm (a = 6.2269(1) Å, c = 12.3122(1) Å, Z = 2) and is isostructural with Ca6FeN5 and Ca6GaN5. Manganese(III) forms trigonal planar [MnN3]6- units analogous to carbonate anions, which lie in planes parallel to the c axis, sandwiched between layers of Ca-N polyhedra. Calcium is coordinated to five...

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Publication status:
Published

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Publisher copy:
10.1021/ic00125a017

Authors


GREGORY, D More by this author
EDWARDS, P More by this author
SIDDONS, D More by this author
Journal:
INORGANIC CHEMISTRY
Volume:
34
Issue:
21
Pages:
5195-5198
Publication date:
1995-10-11
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:4ac4ef53-f19a-4de8-8c68-e933ca776bba
Source identifiers:
46670
Local pid:
pubs:46670
Language:
English

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