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The heterocubane [TerSnAs]4

Abstract:

The synthesis of a novel heterocubane [RSnE]4 was successful for E = As, while for E = P differing behaviour was observed. Aryl-substituted chlorostannylenes were treated with salts of heavy cyanate homologues PCO− and AsCO−. The reaction with AsCO− salts afforded primarily [TerSnAs]4 (Ter = 2,6-dimesitylphenyl). In contrast, the reaction of TerSnCl with NaPCO proceeded considerably less cleanly affording a mixture of products. The main product was putatively a neutral [Ter4Sn4P4] compound, h...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1039/c8dt01993b

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More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Role:
Author
ORCID:
0000-0002-7831-1410
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Inorganic Chemistry
Oxford college:
Lady Margaret Hall; Lady Margaret Hall
Role:
Author
ORCID:
0000-0002-7311-1663
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Dalton Transactions Journal website
Volume:
47
Issue:
27
Pages:
8879-8883
Publication date:
2018-06-15
Acceptance date:
2018-06-13
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
Pubs id:
pubs:859150
URN:
uri:4a9ddd09-ed96-4069-b62d-05a932982f2f
UUID:
uuid:4a9ddd09-ed96-4069-b62d-05a932982f2f
Local pid:
pubs:859150
Language:
English

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